Extended Generic Nature of Surface Entropy

Details Extended Generic Nature of Surface Entropy Extended Generic Nature of Surface Entropy

2003-01-28

arxiv.org/abs/cond-mat/0301538v1

Langmuir, 19(2) (2003) 211-213

Physics

Condensed Matter

Statistical Mechanics

three pages, three figures

Scientific paper

The recent empirical correlation for the surface tension is further investigated for universality. C5-C8 liquid hydrocarbons, for which accurate surface tension data over the complete liquid range are available, are used. Functional reduced surface entropy is derived, which is in the general form of Trouton's rule. It is characterized by the critical exponent of surface tension and is valid with the unique value 0.9990 at any temperature from freezing to critical temperature of the liquid hydrocarbons. Relation to generic nature of surface entropy is pursued.

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