Excited-state relaxations and Franck-Condon shift in Si quantum dots

Physics – Condensed Matter – Materials Science

Scientific paper

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Scientific paper

10.1103/PhysRevB.68.033313

Excited-state relaxations in molecules are responsible for a red shift of the absorption peak with respect to the emission peak (Franck-Condon shift). The magnitude of this shift in semiconductor quantum dots is still unknown. Here we report first-principle calculations of excited-state relaxations in small (diameter < 2.2 nm) Si nanocrystals, showing that the Franck-Condon shift is surprisingly large (~60 meV for a 2.2 nm-diameter nanocrystal). The physical mechanism of the excited-state relaxations changes abruptly around 1 nanoeter in size, providing a clear demarcation between ``molecules'' and ``nanocrystals''.

No associations

LandOfFree

Say what you really think

Search LandOfFree.com for scientists and scientific papers. Rate them and share your experience with other people.

Rating

Excited-state relaxations and Franck-Condon shift in Si quantum dots does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Excited-state relaxations and Franck-Condon shift in Si quantum dots, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Excited-state relaxations and Franck-Condon shift in Si quantum dots will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFWR-SCP-O-433557

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.