Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2002-07-15
Physics
Condensed Matter
Statistical Mechanics
4 pages, 2 figures
Scientific paper
10.1103/PhysRevE.67.036104
We derive analytical expressions for the reactivity of a Single-File System with fast diffusion and adsorption and desorption at one end. If the conversion reaction is fast, then the reactivity depends only very weakly on the system size, and the conversion is about 100%. If the reaction is slow, then the reactivity becomes proportional to the system size, the loading, and the reaction rate constant. If the system size increases the reactivity goes to the geometric mean of the reaction rate constant and the rate of adsorption and desorption. For large systems the number of nonconverted particles decreases exponentially with distance from the adsorption/desorption end.
Jansen A. P. J.
Lukkien J. J.
Nedea S. V.
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