Exact Results for Kinetics of Catalytic Reactions

Details Exact Results for Kinetics of Catalytic Reactions Exact Results for Kinetics of Catalytic Reactions

1995-08-25

arxiv.org/abs/cond-mat/9508123v1

Physics

Condensed Matter

4 pages, RevTeX, no figures

Scientific paper

10.1103/PhysRevE.53.R3009

The kinetics of an irreversible catalytic reaction on substrate of arbitrary dimension is examined. In the limit of infinitesimal reaction rate (reaction-controlled limit), we solve the dimer-dimer surface reaction model (or voter model) exactly in arbitrary dimension $D$. The density of reactive interfaces is found to exhibit a power law decay for $D<2$ and a slow logarithmic decay in two dimensions. We discuss the relevance of these results for the monomer-monomer surface reaction model.

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