Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2008-02-20
Phys. Rev. B. 79, 125116 (2009)
Physics
Condensed Matter
Strongly Correlated Electrons
8 pages, 6 figures
Scientific paper
10.1103/PhysRevB.79.125116
We investigate electronic transport through pentacene thin-films intercalated with potassium. From temperature-dependent conductivity measurements we find that potassium-intercalated pentacene shows metallic behavior in a broad range of potassium concentrations. Surprisingly, the conductivity exhibits a re-entrance into an insulating state when the potassium concentration is increased past one atom per molecule. We analyze our observations theoretically by means of electronic structure calculations, and we conclude that the phenomenon originates from a Mott metal-insulator transition, driven by electron-electron interactions.
Brocks Geert
Craciun Monica Felicia
Giovannetti Gianluca
Morpurgo Alberto F.
Rogge Sven
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