Evidence for distinct polymer chain orientations in KC60 and RbC60

Details Evidence for distinct polymer chain orientations in KC60 and RbC60 Evidence for distinct polymer chain orientations in KC60 and RbC60

1998-09-24

arxiv.org/abs/cond-mat/9809325v1

Physics

Condensed Matter

To be published in Phys. Rev. Lett

Scientific paper

10.1103/PhysRevLett.81.4420

The KC60 and RbC60 polymer phases exhibit contrasting electronic properties while powder diffraction studies have revealed no definite structural difference. We have performed single crystal X-ray diffraction and diffuse scattering studies of these compounds. It is found that KC60 and RbC60 possess different chain orientations about their axes, which are described by distinct space groups Pmnn and I2/m, respectively. Such a structural difference will be of great importance to a complete understanding of the physical properties.

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