Equation of State, Stability, Anisotropy and Nonlinear Elasticity of Diamond-Cubic (ZB) Silicon by Phonon Imaging at High Pressure

Physics – Condensed Matter – Materials Science

Scientific paper

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Scientific paper

Experimental phonon imaging in diamond anvils cell is demonstrated to be an adequate tool to extract the complete set of elastic constants of single-crystalline silicon up to the ZB$\rightarrow \beta-$Sn transition (10 GPa). Contrary to what was commonly admitted, we demonstrate that the development of the strain-energy density in terms of strains cannot be stopped, for silicon, after the terms containing the third-order elastic constants. Nonlinear elasticity, degree of anisotropy and pressure-induced mechanical stability of the cubic silicon structure are thus revisited and investigated in more detail.

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