Physics – Condensed Matter – Materials Science
Scientific paper
2008-01-24
Solid State Sciences 10 (2008) 1387-1394
Physics
Condensed Matter
Materials Science
Scientific paper
10.1016/j.solidstatesciences.200
Magnetic properties of single crystals of the heterometallic complex [Cu(bpy)$_3$]$_2$[Cr(C$_2$O$_4$)$_3$]NO$_3\cdot $9H$_2$O (bpy = 2,2'-bipyridine) have been investigated. From the recorded EPR spectra, the spin-Hamiltonian parameters have been determined. The magnetization measurements have shown magnetic anisotropy at low temperatures, which has been analysed as a result of the zero-field splitting of the Cr$^{\mathrm{III}}$ ion. By fitting the exactly derived magnetization expression to the measured magnetization data, the axial zero-field splitting parameter, D, has been calculated. Comparing to the EPR measurements, it has been confirmed that $D$ can be determined from the measurements of the macroscopic magnetization on the single crystals.
Juric Marijana
Novosel Nikolina
Pajic Damir
Perić Berislav
Planinic Pavica
No associations
LandOfFree
EPR and magnetization studies on single crystals of a heterometallic (Cu^{II}} and Cr^{III}) complex: zero-field splitting determination does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with EPR and magnetization studies on single crystals of a heterometallic (Cu^{II}} and Cr^{III}) complex: zero-field splitting determination, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and EPR and magnetization studies on single crystals of a heterometallic (Cu^{II}} and Cr^{III}) complex: zero-field splitting determination will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-283288