Enhanced Pressure Dependence of Magnetic Exchange in A2+[V2]O4 Spinels Approaching the Itinerant Electron Limit

Details Enhanced Pressure Dependence of Magnetic Exchange in A2+[V2]O4 Spinels Approaching the Itinerant Electron Limit Enhanced Pressure Dependence of Magnetic Exchange in A2+[V2]O4 Spinels Approaching the Itinerant Electron Limit

2007-06-11

arxiv.org/abs/0706.1468v1

Physics

Condensed Matter

Strongly Correlated Electrons

Scientific paper

10.1103/PhysRevLett.99.187201

We report a systematic enhancement of the pressure dependence of TN in A2+[V2]O4 spinels as the V-V separation approaches the critical separation for a transition to itinerant-electron behavior. An intermediate phase between localized and itinerant electron behavior is identified in Zn[V2]O4 and Mg[V2]O4 exhibiting mobile holes as large polarons. In Zn[V2]O4, cooperative ordering of V-V pairs below a Ts=TN does not totally suppress the V3+-ion spins at ambient pressure, but makes TN to decrease with pressure. Our results demonstrate that Zn[V2]O4 and Mg[V2]O4 are less localized than previously thought.

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