Encapsulating C59N azafullerene derivatives inside single-wall carbon nanotubes

Details Encapsulating C59N azafullerene derivatives inside single-wall carbon nanotubes Encapsulating C59N azafullerene derivatives inside single-wall carbon nanotubes

2006-02-27

arxiv.org/abs/cond-mat/0602636v1

Carbon 44, 1958-1962 (2006)

Physics

Condensed Matter

Materials Science

To appear in Carbon

Scientific paper

Filling of single-wall carbon nanotubes with C59N azafullerene derivatives is reported from toluene solvent at ambient temperature. The filling is characterized by high resolution transmission electron microscopy and Raman spectroscopy. The filling efficiency is the same as for C60 fullerenes and the tube-azafullerene interaction is similar to the tube-C60 interaction. Vacuum annealing of the encapsulated azafullerene results in the growth of inner tubes, however no spectroscopic signature of nitrogen built in the inner walls is detected.

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