Physics – Condensed Matter – Materials Science
Scientific paper
2005-01-24
Physics
Condensed Matter
Materials Science
16 pages, 3 figures
Scientific paper
10.1063/1.2001130
We report the effect of air exposure on the electronic properties of pentacene single crystals. Air can diffuse reversibly in and out of the crystals and controls the physical properties. We discern two competing mechanisms that modulate the electronic transport. The presence of oxygen increases the hole conduction, as in dark four O2 molecules introduce one charge carrier. This effect is enhanced by the presence of visible light. Contrarily, water, present in ambient air, is incorporated in the crystal lattice and forms trapping sites for injected charges.
Baas Jacob
Jurchescu Oana D.
Palstra Thomas T. M.
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