Electronic Structure of the YH3 Phase from Angle-Resolved Photoemission Spectroscopy

Physics – Condensed Matter – Materials Science

Scientific paper

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Scientific paper

10.1103/PhysRevLett.90.196804

Yttrium can be loaded with hydrogen up to high concentrations causing dramatic structural and electronic changes of the host lattice. We report on angle-resolved photoemission experiments of the Y trihydride phase. Most importantly, we find the absence of metal d-bands at the Fermi level and a set of flat, H-induced bands located at much higher binding energy than predicted, indicating an increased electron affinity at H sites.

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