Electronic Structure of Fullerene Anions

Details Electronic Structure of Fullerene Anions Electronic Structure of Fullerene Anions

1993-11-04

arxiv.org/abs/cond-mat/9311011v1

CRAS (Paris), 318, series II, 283 (1994)

Physics

Condensed Matter

18pp., 1 table and 2 figs, not included, plain TeX, SPhT/93-119

Scientific paper

We study the electronic states of isolated fullerene anions C$^{n-}_{60}$ ($1\le n \le 6$) taking into account the effective interaction between electrons due to exchange of intramolecular phonons. If the vibronic coupling is strong enough such an effect may overwhelm Hund's rule and lead to an ordering of levels that can be interpreted as on-ball pairing, in a manner similar to the pairing in atomic nuclei. We suggest that such effects may be sought in solutions of fulleride ions and discuss recent experimental results.

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