Physics – Condensed Matter – Materials Science
Scientific paper
2011-11-23
Physics
Condensed Matter
Materials Science
arXiv admin note: substantial text overlap with arXiv:1001.5204 by other authors
Scientific paper
Carbon nanotubes are a fraction of the size of transistors used in today's best microchips, as it could reduce power demands and heating in next electronics revolution. Present study investigates the electronic and magnetic structure of multi walled carbon nanotubes (MWCNT) synthesized by chemical vapor deposition technique using near edge x-ray absorption spectroscopy (NEXAFS) measurement at C K-edge and x-ray magnetic circular dichroism (XMCD) at Co and Fe $L_{3,2}$ -edges. NEXAFS at C K-edge shows significant $\pi$-bonding, and Fe(Co) L-edge proves the presence of Co$^{2+}$ and Fe$^{2+}$ in octahedral symmetry, and embedded in C-matrix of MWCNT. Element specific hystersis loops and XMCD spectra clearly shows that these MWCNTs exhibits room temperature ferromagnetism. These measurements elucidated the electronic structure of CNTs and presence of magnetic interactions at room temperature.
Asokan K.
Augustine S.
Brookes Nicholas B.
Chae Keun Hwa
Gautama Sanjeev
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