Electron-Phonon Interactions in C$_{28}$-derived Molecular Solids

Details Electron-Phonon Interactions in C$_{28}$-derived Molecular Solids Electron-Phonon Interactions in C$_{28}$-derived Molecular Solids

2004-02-27

arxiv.org/abs/cond-mat/0403003v2

Physics

Condensed Matter

Superconductivity

Lower quality postscript file for Figure 1 is used in the manuscript in order to meet submission quota for pre-print server. H

Scientific paper

10.1103/PhysRevB.70.140504

We present {\it ab initio} density-functional calculations of molecular solids formed from C$_{28}$-derived closed-shell fullerenes. Solid C$_{28}$H$_4$ is found to bind weakly and exhibits many of the electronic structure features of solid C$_{60}$ with an enhanced electron-phonon interaction potential. We show that chemical doping of this structure is feasible, albeit more restrictive than its C$_{60}$ counterpart, with an estimated superconducting transition temperature exceeding those of the alkali-doped C$_{60}$ solids.

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