Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2004-01-02
Journal of Physical Chemistry B 108, 2509 (2004)
Physics
Condensed Matter
Soft Condensed Matter
To be published in Journal of Physical Chemistry B, 8 pages (double column), 4 figures
Scientific paper
We report a first-principle study of the electronic and conduction properties of a quadruple-helix guanine wire (G4-wire), a DNA-derivative, with inner potassium ions. The analysis of the electronic structure highlights the presence of energy manifolds that are equivalent to the bands of (semi)conducting materials, and reveals the formation of extended electron channels available for charge transport along the wire. The specific metal-nucleobase interactions affect the electronic properties at the Fermi level, leading the wire to behave as an intrinsically p-doped system.
Calzolari Arrigo
Felice Rosa Di
Garbesi Anna
Molinari Elisa
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