Physics – Condensed Matter – Mesoscale and Nanoscale Physics
Scientific paper
2007-04-03
Nano Lett. 7, 1396-1400 (2007)
Physics
Condensed Matter
Mesoscale and Nanoscale Physics
29 pages, 11 figures (includes supp. material)
Scientific paper
10.1021/nl070625w
Single-molecule detection with chemical specificity is a powerful and much desired tool for biology, chemistry, physics, and sensing technologies. Surface-enhanced spectroscopies enable single molecule studies, yet reliable substrates of adequate sensitivity are in short supply. We present a simple, scaleable substrate for surface-enhanced Raman spectroscopy (SERS) incorporating nanometer-scale electromigrated gaps between extended electrodes. Molecules in the nanogap active regions exhibit hallmarks of very high Raman sensitivity, including blinking and spectral diffusion. Electrodynamic simulations show plasmonic focusing, giving electromagnetic enhancements approaching those needed for single-molecule SERS.
Grady Nathaniel K.
Halas Naomi J.
Levin C. S.
Natelson Douglas
Nordlander Peter
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