Effective Field and the Bloch-Siegert Shift at Bihromatic Excitation of Multiphoton EPR

Physics – Condensed Matter – Materials Science

Scientific paper

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6 pages, 5 figures

Scientific paper

10.1134/S0021364006150070

The dynamics of multiphoton transitions in a two-level spin system excited by transverse microwave and longitudinal RF fields with the frequencies w_{mw} and w_{rf}, respectively, is analyzed. The effective time-independent Hamiltonian describing the "dressed" spin states of the "spin + bichromatic field" system is obtained by using the Krylov-Bogoliubov-Mitropolsky averaging method. The direct detection of the time behavior of the spin system by the method of nonstationary nutations makes it possible to identify the multiphoton transitions for resonances w_{0} = w_{mw} + rw_{rf} (w_{0} is the central frequency of the EPR line, r = 1, 2), to measure the amplitudes of the effective fields of these transitions, and to determine the features generated by the inhomogeneous broadening of the EPR line. It is shown that the Bloch-Siegert shifts for multiphoton resonances at the inhomogeneous broadening of spectral lines reduce only the nutation amplitude but do not change their frequencies.

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