Effect of entropy on the dynamics of supercooled liquids: New results from high pressure data

Details Effect of entropy on the dynamics of supercooled liquids: New results from high pressure data Effect of entropy on the dynamics of supercooled liquids: New results from high pressure data

2007-01-23

arxiv.org/abs/cond-mat/0701567v1

Physics

Condensed Matter

Soft Condensed Matter

10 pages 7 figures

Scientific paper

10.1080/14786430600936413

We show that for arbitrary thermodynamic conditions, master curves of the entropy are obtained by expressing S(T,V) as a function of TV^g_G, where T is temperature, V specific volume, and g_G the thermodynamic Gruneisen parameter. A similar scaling is known for structural relaxation times,tau = f(TV^g); however, we find g_G < g. We show herein that this inequality reflects contributions to S(T,V) from processes, such as vibrations and secondary relaxations, that do not directly influence the supercooled dynamics. An approximate method is proposed to remove these contributions, S_0, yielding the relationship tau = f(S-S_0).

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