Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
1997-10-31
Physics
Condensed Matter
Soft Condensed Matter
16 pages, latex
Scientific paper
10.1103/PhysRevE.55.R6344
We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the phase behavior of polymer blends in the presence of external flow. A phenomenological form for the shear modulus for the blend is proposed. The study indicates that a nonlinear dependence of the shear modulus of the blend on the volume fraction of one of the species is crucial for a shift in the stability line to be induced by shear flow.
Balazs Anna C.
Jasnow David
Sun Tao
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