Physics – Condensed Matter – Materials Science
Scientific paper
2007-04-26
Physics
Condensed Matter
Materials Science
6 pages, 4 figures. Submitted for publication
Scientific paper
10.1103/PhysRevLett.99.227201
Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper magnetic ferroelectrics to date. We find that the two proposed mechanisms for FE in multiferroics, lattice- and electronic-based, are simultaneously active in this compound: a large portion of the ferroelectric polarization arises due to quantum-mechanical effects of electron orbital polarization, in addition to the conventional polar atomic displacements. An interesting mechanism for switching the magnetoelectric domains by an electric field via a 180-degree coherent rotation of Mn spins is also proposed.
Dagotto Elbio
Picozzi Silvia
Sanyal Biplab
Sergienko Ivan A.
Yamauchi Kunihiko
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