Disentangling thermal and non-thermal excited states in a charge-transfer insulator by time-and-frequency resolved pump-probe spectroscopy

Physics – Condensed Matter – Strongly Correlated Electrons

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8 pages, 5 figures. Published on Physical Review B.

Scientific paper

10.1103/PhysRevB.80.235129

Time-and-frequency resolved pump-probe optical spectroscopy is used to investigate the effect of the impulsive injection of delocalized excitations through a charge-transfer process in insulating CuGeO3. A large broadening of the charge-transfer edge is observed on the sub-ps timescale. The modification of this spectral feature can not be attributed to the local increase of the effective temperature, as a consequence of the energy absorbed by the pump pulse. The measured modifications of the optical properties of the system are consistent with the creation of a non-thermal state, metastable on the ps timescale, after the pump-induced impulsive modification of the electron interactions.

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