Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg

Details Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg

2010-06-09

arxiv.org/abs/1006.1684v1

J. Phys. Chem. Lett. 1 (2010) 1941-1945

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

11 pages, 4 figures

Scientific paper

10.1021/jz100633d

Direct atomically resolved observation of dynamics deep in the glassy regime has proved elusive for atomic and molecular glasses. Studies below the glass transition temperature Tg are especially rare due to long waiting times required to observe dynamics. Here we directly visualize surface glass dynamics deep in the glassy regime. We analyze scanning tunneling microscopy movies of the surface of metallic glasses with time resolution as fast as 1 minute and extending up to 1,000 minutes. Rearrangements of surface cluster occur almost exclusively by two-state hopping (P(3-state) ~ 0.06). All clusters are compact structures with a width of 2-8 atomic spacings along the surface plane. The two-state dynamics is both spatially and temporally heterogeneous. We estimate an average activation free energy of 14 kBT for surface clusters.

Affiliated with

Also associated with

No associations

Rating

Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-39229