Diffusion-limited loop formation of semiflexible polymers: Kramers theory and the intertwined time scales of chain relaxation and closing

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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Europhys. Lett., 2003 (in press). 8 pages, 3 figures. See also, physics/0101087 for physicist's approach to and the importance

Scientific paper

10.1209/epl/i2003-00219-7

We show that Kramers rate theory gives a straightforward, accurate estimate
of the closing time $\tau_c$ of a semiflexible polymer that is valid in cases
of physical interest. The calculation also reveals how the time scales of chain
relaxation and closing are intertwined, illuminating an apparent conflict
between two ways of calculating $\tau_c$ in the flexible limit.

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