Physics – Condensed Matter – Materials Science
Scientific paper
2005-06-27
Journal Of Physics-Condensed Matter 17 (2005) S4075
Physics
Condensed Matter
Materials Science
soumis \`a J.Phys. Cond. Matt. special issue on "Diffusion in Liquids, Polymers, Biophysics and Chemical Dynamics"
Scientific paper
We study the influence of the boundary conditions at the solid liquid interface on diffusion in a confined fluid. Using an hydrodynamic approach, we compute numerical estimates for the diffusion of a particle confined between two planes. Partial slip is shown to significantly influence the diffusion coefficient near a wall. Analytical expressions are derived in the low and high confinement limits, and are in good agreement with numerical results. These calculations indicate that diffusion of tagged particles could be used as a sensitive probe of the solid-liquid boundary conditions.
Barrat Jean Louis
Bocquet Lyderic
Joly Laurent
Saugey Anthony
Ybert Christophe
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