Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2004-10-09
European Physical Journal E, 17, 485-491 (2005)
Physics
Condensed Matter
Soft Condensed Matter
19 pages, 5 figures
Scientific paper
10.1140/epje/i2005-10023-9
Kinetics of conformational change of a semiflexible polymer under mechanical external field were investigated with Langevin dynamics simulations. It is found that a semiflexible polymer exhibits large hysteresis in mechanical folding/unfolding cycle even with a slow operation, whereas in a flexible polymer, the hysteresis almost disappears at a sufficiently slow operation. This suggests that the essential features of the structural transition of a semiflexible polymer should be interpreted at least on a two-dimensional phase space. The appearance of such large hysteresis is discussed in relation to different pathways in the loading and unloading processes. By using a minimal two-variable model, the hysteresis loop is described in terms of different pathways on the transition between two stable states.
Ohta Takao
Yoshikawa Kenichi
Yoshinaga Natsuhiko
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