Dielectric Screening in a Spherical Cavity

Details Dielectric Screening in a Spherical Cavity Dielectric Screening in a Spherical Cavity

2008-07-09

arxiv.org/abs/0807.1553v1

Physics

Classical Physics

15 Pages, 5 Figures, To be submitted to J. Phys. A. Uses iopart.cls

Scientific paper

10.1088/1751-8113/41/37/375402

In this work we examine the electrostatic screening potential due to a point charge located off-centre in a spherical dielectric cavity. This potential is expanded for the case in which the dielectric constant $\epsilon$ is large, several methods of finding the terms in the expansion are investigated, and closed-form expressions are found through third order in $\epsilon$ along with error bounds. Finally, possible uses of these expressions in molecular dynamics simulations of isolated charged molecules is discussed.

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