Determination of O2(a1Delta g) and O2(b1Sigma + g) yields in the reaction O + ClO yields CL + O2 - Implications for photochemistry in the atmosphere of Venus

Details Determination of O2(a1Delta g) and O2(b1Sigma + g) yields in the reaction O + ClO yields CL + O2 - Implications for photochemistry in the atmosphere of Venus Determination of O2(a1Delta g) and O2(b1Sigma + g) yields in the reaction O + ClO yields CL + O2 - Implications for photochemistry in the atmosphere of Venus

Sep 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987georl..14..949l&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 14, Sept. 1987, p. 949-952.

Physics

11

Atmospheric Chemistry, Chlorine Oxides, Oxygen Atoms, Photochemical Reactions, Quantum Efficiency, Venus Atmosphere, Chemiluminescence, Reaction Products, Venus, Oxygen, Photochemistry, Atmosphere, Laboratory Studies, Reactions, Production Rate, Airglow, Origin, Formation, Experiments, Simulations, Mesosphere, Photolysis, Sulfur Dioxide, Chemiluminescence, Source, Computer Methods

Scientific paper

A discharge flow apparatus with chemiluminescence detector has been used to study the reaction O+ClO→Cl+O2*, where O2*= O2(a1Δg) or O2(b1Σ+g). The observed O2(a1Δg) airglow of Venus cannot be explained in the context of standard photochemistry using the authors' experimental results and those reported in recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the mesosphere of Venus is suggested.

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