Crystallization and phase-separation in non-additive binary hard-sphere mixtures

Details Crystallization and phase-separation in non-additive binary hard-sphere mixtures Crystallization and phase-separation in non-additive binary hard-sphere mixtures

1999-11-23

arxiv.org/abs/cond-mat/9911384v1

Phys. Rev. E. 61, R1028 (2000)

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 4 figures, to appear in Phys. Rev. E

Scientific paper

10.1103/PhysRevE.61.R1028

We calculate for the first time the full phase-diagram of an asymmetric
non-additive hard-sphere mixture. The non-additivity strongly affects the
crystallization and the fluid-fluid phase-separation. The global topology of
the phase-diagram is controlled by an effective size-ratio y_{eff}, while the
fluid-solid coexistence scales with the depth of the effective potential well.

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