Physics – Condensed Matter – Materials Science
Scientific paper
2002-03-31
Physics
Condensed Matter
Materials Science
4 pages, 4 figures
Scientific paper
10.1103/PhysRevB.66.014518
Precise structural information on the Mg1-xAlxB2 superconductors in the vicinity of x 0.5 is derived from high-resolution synchrotron X-ray powder diffraction measurements. We find that a hexagonal superstructure, accompanied by doubling of the c-axis, ordering of Mg and Al in alternating layers, and a shift of the B layers towards Al by ~0.1 A, is formed. The unusually large width of the (001/2) superlattice peak implies the presence of microstrain broadening, arising from anisotropic stacking of Al and Mg layers and/or structural modulations within the ab plane. The ordered phase survives only over a limited range of compositions away from the optimum x= 0.5 doping level.
Arvanitidis I.
Fitch Andrew N.
Margadonna Serena
Papavassiliou Georgios
Pissas Michael
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