Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2004-02-27
Phys. Rev. B. 69, 224105 (2004)
Physics
Condensed Matter
Strongly Correlated Electrons
5 pages, 6 figures
Scientific paper
10.1103/PhysRevB.69.224105
The crystal structure of the layered, perovskite-related LaTiO_3.41 (La_5Ti_5O_{17+\delta}) has been studied by synchrotron powder x-ray diffraction under hydrostatic pressure up to 27 GPa (T = 295 K). The ambient-pressure phase was found to remain stable up to 18 GPa. A sluggish, but reversible phase transition occurs in the range 18--24 GPa. The structural changes of the low-pressure phase are characterized by a pronounced anisotropy in the axis compressibilities, which are at a ratio of approximately 1:2:3 for the a, b, and c axes. Possible effects of pressure on the electronic properties of LaTiO_3.41 are discussed.
Hanfland Michael
Kuntscher Christine A.
Lichtenberg F.
Loa Ingo
Syassen K.
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