Physics – Condensed Matter – Superconductivity
Scientific paper
2004-05-21
Physics
Condensed Matter
Superconductivity
To be published in Solid State Communications (2004)
Scientific paper
10.1016/j.ssc.2004.04.047
Polycrystalline La2-xPrxCa2xBa2Cu4+2xOz (LPCaBCO) compounds with x = 0.1 - 0.5 were synthesized by solid-state reaction method and studied by room temperature X-ray diffraction, dc resistivity, dc magnetization and iodometry. The superconducting transition temperatures in these tetragonal triple perovskite compounds increases from 32 to 62 K (Tconset values) with increasing dopant concentration. The mixing of rare earth La3+ and Pr3+/4+ ions at rare earth site (La3+) along with substitution of divalent Ca2+ results in the shrinkage of unit cell volume. The contraction of unit cell volume due to larger ion being substituted by smaller ions, gives rise to creation of pinning centers in the unit cell leading to increase in critical current density and flux pinning
Kuberkar D. G.
Rayaprol Sudhindra
Shah Nimish A.
Thaker C. M.
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