Counterions at charge-modulated substrates

Details Counterions at charge-modulated substrates Counterions at charge-modulated substrates

2002-10-12

arxiv.org/abs/cond-mat/0210281v1

Europhys. Lett. 57, 911 (2002)

Physics

Condensed Matter

Soft Condensed Matter

7 pages

Scientific paper

10.1209/epl/i2002-00597-2

We consider counterions in the presence of a single planar surface with a spatially inhomogeneous charge distribution using Monte-Carlo simulations and strong-coupling theory. For high surface charges, multivalent counterions, or pronounced substrate charge modulation the counterions are laterally correlated with the surface charges and their density profile deviates strongly from the limit of a smeared-out substrate charge distribution, in particular exhibiting a much increased laterally averaged density at the surface.

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