Corresponding States of Structural Glass Formers

Details Corresponding States of Structural Glass Formers Corresponding States of Structural Glass Formers

2008-11-15

arxiv.org/abs/0811.2450v2

J. Phys. Chem. B. 113, 5563 (2009)

Physics

Condensed Matter

Statistical Mechanics

6 pages, 2 figures. Updated References, Table Values, Submitted for Publication

Scientific paper

10.1021/jp810362g

The variation with respect to temperature T of transport properties of 58 fragile structural glass forming liquids (68 data sets in total) are analyzed and shown to exhibit a remarkable degree of universality. In particular, super-Arrhenius behaviors of all super-cooled liquids appear to collapse to one parabola for which there is no singular behavior at any finite temperature. This behavior is bounded by an onset temperature To above which liquid transport has a much weaker temperature dependence. A similar collapse is also demonstrated, over the smaller available range, for existing numerical simulation data.

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