Physics – Condensed Matter – Materials Science
Scientific paper
2010-09-22
J. Phys.: Condens. Matter Vol. 21 page 072101 (2009)
Physics
Condensed Matter
Materials Science
18 pages, 4 figures
Scientific paper
10.1088/0953-8984/21/7/072101
A wide variation in the charge transport properties of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) films is attributed to the degree of phase-segregation of the excess insulating polyanion. The results indicate that the charge transport in PEDOT-PSS can vary from hopping to critical regime of the metal-insulator transition, depending on the subtle details of morphology. The extent of electrical-connectivity in films, directly obtained from a temperature dependent high-frequency transport study, indicates various limiting factors to the transport, which are correlated with the phase separation process. The low temperature magnetotransport further supports this morphology-dependent transport scenario.
Jaiswal Manu
Menon Reghu
Suchand Sangeeth C. S.
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