Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2008-12-17
J. Phys. D: Appl. Phys. 42, 175505 (2009)
Physics
Condensed Matter
Soft Condensed Matter
Scientific paper
10.1088/0022-3727/42/17/175505
We demonstrate a simple and robust methodology for measuring and analyzing the polarization impedance appearing at interface between electrodes and ionic solutions, in the frequency range from 1 to $10^6$ Hz. The method assumes no particular behavior of the electrode polarization impedance and it only makes use of the fact that the polarization effect dies out with frequency. The method allows a direct and un-biased measurement of the polarization impedance, whose behavior with the applied voltages and ionic concentration is methodically investigated. Furthermore, based on the previous findings, we propose a protocol for correcting the polarization effect in low frequency Dielectric Spectroscopy measurements of colloids. This could potentially lead to the quantitative resolution of the $\alpha$-dispersion regime of live cells in suspension.
Bot Corina
Prodan Camelia
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