Cooperative mercury motion in the ionic conductor Cu2HgI4

Details Cooperative mercury motion in the ionic conductor Cu2HgI4 Cooperative mercury motion in the ionic conductor Cu2HgI4

2012-01-05

arxiv.org/abs/1201.1182v2

Physics

Condensed Matter

Materials Science

5+2 pages (including supplemental material

Scientific paper

We present the observation of glass-like dynamic correlations of mobile mercury ions in the fast ion conductor Cu2HgI4, detected in both NMR and nonlinear conductivity experiments. The results show that dynamic cooperativity appears in systems seemingly unrelated to glassy and soft arrested materials. A simple kinetic two-component model is proposed, which seems to provide a good description of the cooperative ionic dynamics.

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