Contact values for disparate-size hard-sphere mixtures

Details Contact values for disparate-size hard-sphere mixtures Contact values for disparate-size hard-sphere mixtures

2009-02-04

arxiv.org/abs/0902.0683v2

Mol. Phys. 107, 685-691 (2009)

Physics

Condensed Matter

Soft Condensed Matter

12 pages, 10 figures; v2: typo in Eq. (28) corrected

Scientific paper

10.1080/00268970902852665

A universality ansatz for the contact values of a multicomponent mixture of additive hard spheres is used to propose new formulae for the case of disparate-size binary mixtures. A comparison with simulation data and with a recent proposal by Alawneh and Henderson for binary mixtures shows reasonably good agreement with the predictions for the contact values of the large-large radial distribution functions. A discussion on the usefulness and limitations of the new proposals is also presented.

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