Conformational Transitions of Non-Grafted Polymers Near an Adsorbing Substrate

Details Conformational Transitions of Non-Grafted Polymers Near an Adsorbing Substrate Conformational Transitions of Non-Grafted Polymers Near an Adsorbing Substrate

2005-02-04

arxiv.org/abs/cond-mat/0502138v1

Phys. Rev. Lett. 95, 058102(1-4) (2005).

Physics

Condensed Matter

Statistical Mechanics

4 pages, revtex.cls, 10 postscript figures, author information under http://www.physik.uni-leipzig.de/index.php?id=22

Scientific paper

10.1103/PhysRevLett.95.058102

We have performed multicanonical chain-growth simulations of a polymer interacting with an adsorbing surface. The polymer, which is not explicitly anchored at the surface, experiences a hierarchy of phase transitions between conformations binding and non-binding with the substrate. We discuss the phase diagram in the temperature-solubility plane and highlight the transition ``path'' through the free-energy landscape.

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