Conflict between trajectories and density description: the statistical source of disagreement

Details Conflict between trajectories and density description: the statistical source of disagreement Conflict between trajectories and density description: the statistical source of disagreement

2002-12-27

arxiv.org/abs/cond-mat/0212614v1

Physics

Condensed Matter

Statistical Mechanics

8 pages, no figures

Scientific paper

We study an idealized version of intermittent process leading the fluctuations of a stochastic dichotomous variable $\xi$. It consists of an overdamped and symmetric potential well with a cusp-like minimum. The right-hand and left-hand portions of the potential corresponds to $\xi = W$ and $\xi = -W$, respectively. When the particle reaches this minimum is injected back to a different and randomly chosen position, still within the potential well. We build up the corresponding Frobenius-Perron equation and we evaluate the correlation function of the stochastic variable $\xi$, called $\Phi_{\xi}(t)$. We assign to the potential well a form yielding $\Phi_{\xi}(t) = (T/(t + T))^{\beta}$, with $\beta > 0$. We limit ourselves to considering correlation functions with an even number of times, indicated for concision, by $<12>$, $<1234>$ and, more, in general, by $<1 ... 2n>$. The adoption of a treatment based on density yields $<1 ... 2n > = < 1 2 > ... < (2n-1) 2n>$. We study the same dynamic problem using trajectories, and we establish that the resulting two-time correlation function coincides with that afforded by the density picture, as it should. We then study the four-times correlation function and we prove that in the non-Poisson case it departs from the density prescription, namely, from $<1234 > = < 12 > < 34>$. We conclude that this is the main reason why the two pictures yield two different diffusion processes, as noticed in an earlier work [M. Bologna, P. Grigolini, B.J. West, Chem. Phys. {\bf 284}, (1-2) 115-128 (2002)].

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