Physics – Condensed Matter – Materials Science
Scientific paper
2011-02-08
Chemistry Letters 40, 255 (2011)
Physics
Condensed Matter
Materials Science
4 pages
Scientific paper
10.1246/cl.2011.255
Graphene oxide (GO) is one of chemically modified graphenes and has been extensively investigated worldwide. A monolayer sheet of GO can be chemically produced in solution and it has been expected to be adaptable to a wide variety of applications. Most of works have focused on fabrication and reduction processes of GO, while its intrinsic property has not been explored in detail. We have succeeded in fabricating large scale GO nanosheets reproducibly. In the present work, we observed GO nanosheets by conductive atomic force microscopy. The current image is useful to monitor the GO thickness as well as wrinkles and folds in the nanosheet with high contrast. In addition to the current images, local I-V characteristics of the GO sheet were measured with the conductive cantilever. Based on the applied electric filed dependence, the conduction normal to the GO sheet could be described in terms of Poole Frenkel emission mechanism and the relative permittivity of GO is evaluated to be 4.8.
Kanamori Yoshio
Obata Seiji
Saiki Koichiro
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