Computing Counterion Densities at Intermediate Coupling

Details Computing Counterion Densities at Intermediate Coupling Computing Counterion Densities at Intermediate Coupling

2005-01-20

arxiv.org/abs/cond-mat/0501498v1

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 1 figure

Scientific paper

10.1103/PhysRevE.73.041512

By decomposing the Coulomb interaction into a long distance component appropriate for mean-field theory, and a nonmean-field short distance component, we compute the counterion density near a charged surface for all values of the counterion coupling parameter. A modified strong-coupling expansion that is manifestly finite at all coupling strengths is used to treat the short distance component. We find a nonperturbative correction related to the lateral counterion correlations that modifies the density at intermediate coupling.

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