Physics – Condensed Matter – Materials Science
Scientific paper
2012-04-19
Physical Review B 85, 144103 (2012)
Physics
Condensed Matter
Materials Science
14 pages, 3 figures, 1 table
Scientific paper
10.1103/PhysRevB.85.144103
We have investigated by means of high-pressure x-ray diffraction the structural stability of Pd2Mo3N, Ni2Mo3C0.52N0.48, Co3Mo3C0.62N0.38, and Fe3Mo3C. We have found that they remain stable in their ambient-pressure cubic phase at least up to 48 GPa. All of them have a bulk modulus larger than 330 GPa, being the least compressible material Fe3Mo3C, B0 = 374(3) GPa. In addition, apparently a reduction of compressibility is detected as the carbon content increased. The equation of state for each material is determined. A comparison with other refractory materials indicates that interstitial nitrides and carbides behave as ultra-incompressible materials.
Errandonea Daniel
Gomez Adrian
Gomis Oscar
Ruiz-Fuertes Javier
Sans J. A.
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