Communication: Inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities

Details Communication: Inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities Communication: Inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities

2011-09-21

arxiv.org/abs/1109.4486v2

J. Chem. Phys. 135, 181102 (2011)

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 2 figures; v2: Simulation data for one-component hard spheres included in Fig. 1

Scientific paper

10.1063/1.3663206

A possible approximate route to obtain the equation of state of the monodisperse hard-sphere system in the metastable fluid region from the knowledge of the equation of state of a hard-sphere mixture at high densities is discussed. The proposal is illustrated by using recent Monte Carlo simulation data for the pressure of a binary mixture. It is further shown to exhibit high internal consistency.

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