Colloids electrophoresis for strong and weak ion diffusivity

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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4 pages, 4 figures, Phys. Rev. Lett., in press

Scientific paper

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases significantly and displays a mobility maximum on increasing the colloidal charge for all salt concentrations. The electrophoretic mobility of highly charged colloids is also enhanced significantly when ion advection is dominant, leading to a strong heterogeneity in the local electrophoretic response especially at low salt concentration, when ion diffuse layers overlap.

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