Collective excitations in liquid D2 confined within the mesoscopic pores of a MCM-41 molecular sieve

Physics – Condensed Matter – Materials Science

Scientific paper

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6 pages

Scientific paper

10.1103/PhysRevB.73.094206

We present a comparative study of the excitations in bulk and liquid D2 confined within the pores of MCM-41. The material (Mobile Crystalline Material-41) is a silicate obtained by means of a template that yields a partially crystalline structure composed by arrays of nonintersecting hexagonal channels of controlled width having walls made of amorphous SiO2. Its porosity was characterized by means of adsorption isotherms and found to be composed by a regular array of pores having a narrow distribution of sizes with a most probable value of 2.45 nm. The assessment of the precise location of the sample within the pores is carried out by means of pressure isotherms. The study was conducted at two pressures which correspond to pore fillings above the capillary condensation regime. Within the range of wave vectors where collective excitations can be followed up (0.3

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