Coarse-grained Description of Polymer Blends as Interacting Soft-Colloidal Particles

Details Coarse-grained Description of Polymer Blends as Interacting Soft-Colloidal Particles Coarse-grained Description of Polymer Blends as Interacting Soft-Colloidal Particles

2004-11-18

arxiv.org/abs/cond-mat/0411497v1

Physics

Condensed Matter

Statistical Mechanics

27 REVTex4 pages, 8 PostScript figures, 1 table accepted for publication in Journal of Chemical Physics

Scientific paper

10.1063/1.1835271

We present a theoretical approach which maps polymer blends onto mixtures of soft-colloidal particles. The analytical mesoscale pair distribution functions reproduce well data from united atom molecular dynamics simulations of polyolefin mixtures without fitting parameters. The theory exactly recovers the analytical expressions for density and concentration fluctuation structure factors of soft colloidal mixtures (liquid alloys).

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