Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2010-08-23
Physics
Condensed Matter
Statistical Mechanics
Phys. Rev. Lett. PACS 51.30.+i 8 pages 3 figs. June 16 2010
Scientific paper
A closed virial equation-of-state for the low density fluid phase of hard disks is obtained from the known virial coefficients. The equation exhibits 6-figure accuracy for the thermodynamic (MD) pressure up to the reduced number density ~ 0.4 Interpolation of the discrepancy at higher densities indicates a higher-order thermodynamic phase transition at the extensive-intensive free-volume percolation transition previously located by Hoover et al. (JCP 70 1837 1979)
Beris Anthony
Woodcock Leslie V.
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