Charge transfer gap for T'-RE2CuO4 and T-La2CuO4 as estimated from Madelung potential calculations

Details Charge transfer gap for T'-RE2CuO4 and T-La2CuO4 as estimated from Madelung potential calculations Charge transfer gap for T'-RE2CuO4 and T-La2CuO4 as estimated from Madelung potential calculations

2006-03-15

arxiv.org/abs/cond-mat/0603403v1

Physics

Condensed Matter

Superconductivity

12 pages, 1 figure, Proceedings of ISS 2005

Scientific paper

10.1016/j.physc.2006.03.087

T'-RE2CuO4 (RE: rare-earth element), after appropriate "reduction", has fairly high conductivity and also exhibits clear Fermi edge in photoemission spectroscopy. To clarify the origin of conductivity in the T' mother compounds, we evaluated the unscreened charge-transfer gap for T'-RE2CuO4 and T-La2CuO4. The value of charge-transfer gap for T'-compounds almost linearly decreases with increasing the ionic radius of RE from 12.24 eV for T'-Tm2CuO4 to 9.90 eV for T'-La2CuO4. The results qualitatively explain metallic conductivity in T'-RE2CuO4 for large RE.

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