Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2007-05-10
Phys. Rev. Lett. 99, 118302 (2007).
Physics
Condensed Matter
Soft Condensed Matter
4 pages
Scientific paper
10.1103/PhysRevLett.99.118302
We analyze theoretically the electrostatic interaction of surface-charged colloids at water interfaces with special attention to the experimentally relevant case of large charge densities on the colloid-water interface. Whereas linear theory predicts an effective dipole potential the strength of which is proportional to the square of the product of charge density and screening length, nonlinear charge renormalization effects change this dependence to a weakly logarithmic one. These results appear to be particularly relevant for structure formation at air-water interfaces with arbitrarily shaped colloids.
Dietrich Sarah
Frydel Derek
Oettel Martin
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